Proceedings Volume 6766

Optoelectronic Devices: Physics, Fabrication, and Application IV

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Proceedings Volume 6766

Optoelectronic Devices: Physics, Fabrication, and Application IV

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Volume Details

Date Published: 25 September 2007
Contents: 6 Sessions, 15 Papers, 0 Presentations
Conference: Optics East 2007
Volume Number: 6766

Table of Contents

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Table of Contents

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  • Front Matter: Volume 6766
  • Nanostructures
  • Optical Sensors
  • Novel Materials
  • Novel Devices
  • Poster Session
Front Matter: Volume 6766
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Front Matter: Volume 6766
This PDF file contains the front matter associated with SPIE Proceedings Volume 6766, including the Title Page, Copyright information, Table of Contents, and the Conference Committee listing.
Nanostructures
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Enhanced luminescence of top-emission organic light emitting diodes with ZnS/Ag/ZnS structure
Wei-Fan Liao, Jei Huang, Chih-Jui Ni, et al.
The effect of ZnS/Ag/ZnS multiple-layer coating on the top-emitting top-cathode organic light emitting diodes (OLED) was studied. The OLED device consisted of Ag/CuPc:F4-TCNQ/NPB/Alq3/BCP/LiF/Al layers. All organic layers and electrodes were fabricated by thermal evaporation. F4-TCNQ was doped in the hole-injection layer (CuPc) to enhance hole injection, since the energy barrier between Ag and CuPc was high. ZnS layer was first deposited on the top cathode (Al) and found to enhance the light emission of the OLED by 50% (from 10,000 cd/m2 to 15,000 cd/m2). The high-refractive index dielectric material as a capping layer enhances light output for the semitransparent cathode. ZnS/Ag/ZnS multi-layer cathode with photon tunneling characteristics were added on top of Al cathode, and found to further enhance the light emission up to 20,000 cd/m2 at 13V for Al/ZnS/Ag/ZnS (17/37/8/37 nm) layers with maximum current efficiency of 2.6 cd/A. Coupling of surface plasmon modes may occur in the ZnS/Ag/ZnS structure. By increasing Ag layer thickness to compensate the reduction of Al layer thickness, the Al/ZnS/Ag/ZnS (7/37/15/37 nm) cathode was used, and found to achieve the maximum brightness of 31,000cd/m2 at 15V and a maximum current efficiency at 5.6 cd/A. The increase of luminescence efficiency is likely due to high photon tunneling efficiency of Ag as well as its high electric conductivity improving the electron injection. Keywords: OLED, top emission, top cathode, tunneling, surface plasmon.
Coherent optical manipulation of a single spin state in a charged quantum dot: theory and modelling
The optically-induced coherent spin dynamics in a charged quantum dot (QD) is studied theoretically using a new dynamical model for rigorous description of circularly polarized ultrashort optical pulse resonant interactions with the electron-trion system. Generalized pseudospin master equation is derived for description of the time evolution of spin coherences and spin populations in terms of the real state pseudospin (coherence) vector including dissipation in the system through spin relaxation processes. The equation is solved in the time domain self-consistently with the vector Maxwell equations for the optical wave propagation coupled to it via macroscopic medium polarization. Using the model the long-lived electron spin coherence left behind a single resonant ultrashort optical excitation of the electron-trion transition in a charged QD is simulated in the lowand high-intensity Rabi oscillations regime. Signatures of the polarized photoluminescence (PL) resulting from the numerical simulations, such as the appearance of a second echo pulse after the excitation and a characteristic PL trace shape, specific for initial spin-up orientation, are discussed for realization of high-fidelity schemes for coherent readout of a single spin polarization state.
Optical Sensors
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A 130-nm CMOS single-photon avalanche diode
Cristiano Niclass, Marek Gersbach, Robert Henderson, et al.
The first implementation of a single photon avalanche diode (SPAD) is reported in 130nm CMOS technology. The SPAD is fabricated as p+/nwell junction with octagonal shape. Premature edge breakdown is prevented through a guard ring of p-well around the p+ anode. The dynamics of the new device are investigated using both active and passive quenching methods. Single photon detection is achieved by sensing the avalanche using a fast comparator. The SPAD exhibits a maximum photon detection probability of 41% and a typical dark count rate of 100kHz at room temperature. Thanks to its timing resolution of 144ps (FWHM), the SPAD can be used in disparate disciplines, including medical imaging, 3D vision, biophotonics, low-light-illumination imaging, etc.
Highly sensitive refractive index sensors
A chemical and biological sensor based on a free-space waveguide resonant grating optical filter has been developed. Different from the conventional surface plasmon resonance sensors and the conventional waveguide mode sensors, which require either prism coupling or grating coupling, the proposed free-space optical sensor device does not require special separate coupling. The inherent 100% coupling efficiency at resonance can significantly boost probe efficiency. Both simulation and experimental results have demonstrated that the new sensor could deliver a resolution of better than 0.001 to 0.0001 for refractive index sensing, which is enough for detecting various chemical and biological materials. More importantly, under an angular detection scheme, the proposed waveguide resonant grating sensor could be one order's more sensitive than the conventional surface plasmon resonance sensor.
Novel Materials
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Interfacial physics in organic light emitting devices
In this paper, we will present some studies of physics at the interfaces in the organic light emitting devices. The paper can be separated into two parts. First part is the manipulation of interfacial energy structures and electron transport properties of organic semiconductors. The second part is substitution and dopant dependence of electronic structures in organic thin films I will present an investigation of the energy structures and electrical doping mechanisms of the organic semiconductor surface through current-voltage (I-V) characteristics and photoemission spectroscopies. We found that both surface energy structures and transport properties can be manipulated with mix of LiF or Cs2CO3. The I-V characteristics show that the current efficiency is significantly improved with Cs2CO3 doped either at the surface or in the bulk Alq3. As Cs2CO3 doping works efficiently with Al as well as other cathode metals, the interfacial chemistry and carrier injection mechanisms of such cathode structures are compared to that of the conventional LiF thin layers. To understand the mechanisms of the improvement on electron injection, the surface energy levels of metal and organic materials were measured with ultraviolet photoemission spectroscopy (UPS) and the interfacial chemistry was studied with X-ray photoemission spectroscopy (XPS). From UPS spectra, we found that a thin layer of Cs2CO3, as thin as 0.5 A, at the metal and organic ETL interface can bring the Fermi level of Alq3 from mid-gap to less than 0.2 eV below the lowest unoccupied molecular orbital (LUMO), indicating that the Alq3 film at the interface is heavily n-type doped with Cs2CO3 . The smaller gap between the Fermi level and LUMO with Cs2CO3 reduces the electron injection barrier. Strong dipole fields are also found at the surface, which also affects the electron injection considerably. The XPS data further show that Cs ions are dissociated at the interface as soon as Cs2CO3 is deposited on Alq3. The result is different from the case of LiF, in which Al metal is needed for releasing Li ions. With co-evaporation of Cs2CO3 with Alq3 in the bulk as n-doping ETL, the current efficiency can be further improved, which is presumably attributed to the enhancement of the electron transport in the Alq3 films.
Origin of the high photoconductive gain in AlGaN films
Theodore D. Moustakas, Mira Misra
In this paper we report the properties of photoconductive detectors fabricated on GaN and AlGaN films produced by plasma assisted MBE. The spectral dependence of such devices shows a sharp increase over many orders of magnitude at the gap of the semiconductor but it remains constant at shorter wavelengths consistent with absence of surface recombination. The mobility-lifetime product, which is the intrinsic figure of merit of the photoconductive gain, decreases monotonically with the resistivity of GaN films. This result is attributed to the existence of exponential tails due to potential fluctuations arising from stacking faults, point defects and impurities. In the case of AlGaN alloys similar dependence of the mobility-lifetime product on film resistivity has been observed. However, the mobility-lifetime product for films with AlN mole fraction close to 50% is about two orders of magnitude higher than that of GaN films with comparable resistivity. This result was accounted for by the longer lifetime of the photogenerated carriers due to the partial atomic ordering in these alloys. The band structure of the ordered and random domains form a type-II heterostructure and thus photogenerated electrons and holes in these detectors are physically separated, leading to an increase in recombination lifetime.
Novel Devices
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Long-wavelength VCSELs for optical networks and trace-gas monitoring
W. Hofmann, G. Böhm, M. Ortsiefer, et al.
Long-wavelength InGaAlAs-InP vertical-cavity surface-emitting lasers (LW-VCSELs), designed for applications in gas sensing and for optical interconnects are presented. These lasers cover the wavelength-range from 1.3 to 2.3 μm. With 2.3 μm, this is the longest wavelength ever achieved with an InP-based interband laser. Fabricated with a novel highspeed design with reduced parasitics, bandwidths in excess of 11 GHz at 1.55 μm have been achieved. To the best of our knowledge, this is the best dynamic characteristic for a 1.55 μm VCSEL ever presented. As a proof-of-concept one- and two-dimensional arrays have been fabricated with high yield. All devices use for current confinement a buried tunnel junction (BTJ). This concept, together with a dielectric backside reflector with integrated electroplated gold heat sink for thermal management enables continuous wave (CW) operation at room-temperature with typical single-mode output powers above 1 mW. The operation voltage is around 1 V and power consumption is as low as 10 - 20 mW. Error-free data-transmission at 10 Gbit/s over 20 km is demonstrated, which can be readily applied in uncooled Coarse Wavelength Division Multiplex Passive Optical Networks (CWDM PONs). The functionality of tunable diode laser spectroscopy (TDLS) systems is verified by presenting a laser hygrometer using a 1.84 μm wavelength VCSEL.
Recent progress on GaN-based vertical cavity surface emitting lasers
T. C. Lu, C. C. Kao, G. S. Huang, et al.
We report the recent progress of GaN-based VCSELs with two different laser structures. One is a hybrid cavity structure comprised an epitaxial AlN/GaN DBR, an InGaN/GaN MQW active region and a top dielectric DBR. Another is a dielectric cavity structure comprised an InGaN/GaN MQW layer sandwiched by two dielectric DBRs. Both lasers achieved laser action under optical pumping at the room temperature with narrow linewidth. The detailed characteristics of VCSELs will be reported. The status of the electrically pumped VCSEL will also be presented.
Analysis of wavelength-dependent performance variations of GaN-based ultraviolet lasers
We analyze the previously measured performance of a set of gallium nitride based laser diodes emitting ultraviolet light between 360 nm and 380 nm wavelength. The wavelength variation was accomplished by varying the indium content of the InGaN quantum wells which are embedded in AlInGaN barriers. The experiments revealed a strong increase in threshold current with shorter wavelength. Our analysis of this behavior utilizes advanced numerical laser simulation. General models for quaternary AlInGaN material properties are developed and result in good agreement between simulation and measurement. The measured rise in threshold current with shorter wavelength is found to have two main reasons. The first reason is the increased absorption of ultraviolet light inside the laser, mainly within p-doped layers. The second mechanism contributing to the performance deterioration is the leakage of carriers from the active region. In particular, the hole leakage is found to strongly increase with lower indium mole fraction of the quantum well (shorter wavelength), due to the reduced valence band offset.
Poster Session
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Optical triode with quantum dot semiconductor optical amplifiers
Jae-Hoon Huh, Yasuhiko Kuroki, Sayaka Maki, et al.
Semiconductor optical amplifiers (SOAs) having nano-sized quantum dot (QD) particles show attractive features such as the achievement of a steady temperature characteristic, low power consumption, and a high-speed response to the input signal. QD active layers were designed to 15 stacks of InAs QDs, AlGaAs/GaAs double hetero structure. QD-SOAs were fabricated for optical triode that can be used with a 1.3 μm band. Modulation results extracted by input, control and output waveforms support the fact that cross-gain modulation and negative feedback amplification effect can be strongly contributed to obtain essential factors for future application such as dramatical baseline suppression of output signal and satisfying high modulation. Optical triode revealed inverted type characteristics that high output power can readily obtained by be increased quite small amount of input power while output power rarely change though input power increase high. Fulfillment of far more upgraded stable high-speed bit rate was completed by optical triode improved by QD-SOA and it's containing cross-gain modulation effect. 40 Gbps performance optical triode will be the accelerator for realization of the functions of regeneration, reshaping, multiple-wavelength processing, wavelength conversion, and demultiplexing of high-bit rate patterned optical signals.
Guided-mode resonance sensor with extended spatial sensitivity
David Fattal, Mike Sigalas, Anna L. Pyayt, et al.
We propose a novel design for a guided-mode resonance (GMR) grating sensor that extends the sensitivity to a large region of space, possibly several tens of microns away from the grating surface. This type of sensors has high sensitivity in the half-space above the grating, close to the theoretical limit, together with a controllable - potentially very high - quality factor. It relies on a resonance caused by a "confined" mode of a sub-wavelength thick grating slab, a mode that is largely expelled from the grating itself into the grating environment. The small thickness assumption allows us to derive a simple yet accurate analytical model for the sensor behavior, which is tested numerically using a rigorous coupled-wave analysis (RCWA) method as well as in preliminary grating transmission measurements.
Identification device
Jian-Shian Lin, Chih-Chieh Su, Ta-Hsin Chou, et al.
In this Letter, the identification device disclosed in the present invention is comprised of: a carrier and a plurality of pseudo-pixels; wherein each of the plural pseudo-pixels is formed on the carrier and is further comprised of at least a light grating composed of a plurality of light grids. In a preferred aspect, each of the plural light grids is formed on the carrier while spacing from each other by an interval ranged between 50nm and 900nm. As the aforesaid identification device can present specific colors and patterns while it is being viewed by naked eye with respect to a specific viewing angle, the identification device is preferred for security and anti-counterfeit applications since the specific colors and patterns will become invisible when it is viewed while deviating from the specific viewing angle.
Quantum dot resonant tunneling diodes for telecom wavelength single-photon detection
H. W. Li, P. Simmonds, H. E. Beere, et al.
Single photon detection was realized at a telecom wavelength with quantum dot resonant tunneling diodes grown on an InP substrate. The structure contains a AlAs/In0.53Ga0.47As/AlAs quantum well with InAs quantum dots grown on the top AlAs barrier. The single photon detection efficiency of the device under 1310 nm illumination was measured to be about 0.35%±0.07% with a dark count rate of 1.58×10-6 ns-1. This corresponds to an internal efficiency of 6.3%.
Waveguide fabrication in PMMA using a modified cavity femtosecond oscillator
Ke Wang, Denis Klimov, Zbigniew Kolber
Poly Methyl Methacrylate (PMMA) is an advantageous material than glass in oceanographic sensing applications because of its inhospitality for marine organisms. Waveguide sensors fabricated in PMMA are often used to measure the parameters in ocean such as PH, CO2, O2 concentrations, etc. A tightly-focused femtosecond laser is often used to produce such a waveguide or even more complicated structures through the nonlinear effect in the bulk of PMMA, with pulse energy at μJ or mJ level. And such a laser system requires the amplifier from chirped-pulse amplification (CPA). The oscillator itself can produce pulse energy only at nJ level which is under the threshold of nonlinear effect. However, in our experiment, a modification to the oscillator cavity, which elongates the cavity length approximately 3 times and as a result, decreases the repetition rate from 93mHz to 32 mHz, can increase the pulse energy to 15 nJ. Under a tight focusing lens (100x 1.40 microscope objective), such an intensity exceeds the nonlinear threshold of PMMA. Thus, waveguide can be fabricated in PMMA using only a femtosecond oscillator and oceanographic sensors can be also made by this simple technique.