Proceedings Volume 10596

Behavior and Mechanics of Multifunctional Materials and Composites XII

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Proceedings Volume 10596

Behavior and Mechanics of Multifunctional Materials and Composites XII

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Volume Details

Date Published: 11 May 2018
Contents: 16 Sessions, 47 Papers, 32 Presentations
Conference: SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring 2018
Volume Number: 10596

Table of Contents

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Table of Contents

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  • Front Matter: Volume 10596
  • Monday Plenary Session
  • Tuesday Plenary Session
  • Auxetic and Metamaterials
  • Shape Memory Materials I
  • Additive Manufacturing I
  • Origami Materials
  • Dielectrics and Piezolectrics
  • Additive Manufacturing II
  • Shape Memory Materials II
  • Nanocomposites Applications
  • Magnetostrictive Materials
  • Mechanics of Multifunctional Materials
  • Physically Responsive Materials
  • Multifunctional Materials Applications
  • Poster Session
Front Matter: Volume 10596
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Front Matter: Volume 10596
This PDF file contains the front matter associated with SPIE Proceedings Volume 10598, including the Title Page, Copyright information, Table of Contents, and Conference Committee listing.
Monday Plenary Session
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Sensitivity analysis and uncertainty quantification for smart materials and adaptive structures (Conference Presentation)
This presentation will focus on concepts pertaining to sensitivity analysis (SA) and uncertainty quantification (UQ) for smart materials and adaptive structures. Pertinent issues are first illustrated in the context of applications utilizing piezoelectric and shape memory alloy actuators, finite-deformation viscoelastic models, x-ray crystallography, and quantum-informed continuum models. This will demonstrate that the basic UQ goal is to ascertain uncertainties inherent to parameters, initial and boundary conditions, experimental data, and models themselves to make predictions with improved and quantified accuracy. The use of data, to improve the predictive accuracy of models, is central to uncertainty quantification so it is natural to next provide an overview of how Bayesian techniques can be used to construct distributions for model inputs. The discussion will subsequently focus on computational techniques to propagate these distributions through complex models to construct prediction intervals for statistical quantities of interest such as expected stresses in viscoelastic materials, displacements in macro-fiber composites, and strains in SMA tendons. The use of sensitivity analysis to isolate critical model inputs and reduce model complexity is synergistic with uncertainty quantification and will be discussed next. The presentation will conclude with discussion detailing how uncertainty quantification can be used to improve robust control designs for smart material systems.
Tuesday Plenary Session
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Current and future needs and research for composite materials NDE
The use of composite materials continues to increase in the aerospace community due to the potential benefits of reduced weight, increased strength, and manufacturability. The ability to characterize damage in carbon fiber reinforced polymer composite components is required to enable damage progression models capable of yielding accurate remaining life predictions. As these composite structures become larger and more complex, nondestructive evaluation (NDE) techniques capable of quantifying and fully characterizing the material state are needed. This paper will present an overview of current NDE research activities for quantitative characterization of aerospace composites as well as a discussion of future directions in NDE research.
Auxetic and Metamaterials
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Fractional viscoelasticity of soft elastomers and auxetic foams
Hannah Solheim, Eugenia Stanisauskis, Paul Miles, et al.
Dielectric elastomers are commonly implemented in adaptive structures due to their unique capabilities for real time control of a structure’s shape, stiffness, and damping. These active polymers are often used in applications where actuator control or dynamic tunability are important, making an accurate understanding of the viscoelastic behavior critical. This challenge is complicated as these elastomers often operate over a broad range of deformation rates. Whereas research has demonstrated success in applying a nonlinear viscoelastic constitutive model to characterize the behavior of Very High Bond (VHB) 4910, robust predictions of the viscoelastic response over the entire range of time scales is still a significant challenge. An alternative formulation for viscoelastic modeling using fractional order calculus has shown significant improvement in predictive capabilities. While fractional calculus has been explored theoretically in the field of linear viscoelasticity, limited experimental validation and statistical evaluation of the underlying phenomena have been considered. In the present study, predictions across several orders of magnitude in deformation rates are validated against data using a single set of model parameters. Moreover, we illustrate the fractional order is material dependent by running complementary experiments and parameter estimation on the elastomer VHB 4949 as well as an auxetic foam. All results are statistically validated using Bayesian uncertainty methods to obtain posterior densities for the fractional order as well as the hyperelastic parameters.
Boundary modes in quasiperiodic elastic structures
Matheus I. N. Rosa, Raj K. Pal, José R. F. Arruda, et al.
Topological metamaterials are a new class of materials that support topological modes such as edge modes and interface modes, which are commonly immune to scattering and imperfections. This novelty has been the subject of extensive research in many branches of physics such as electronics, photonics, phononics, and acoustics. The nontrivial topological properties related to the presence of topological modes are tipically found in periodic media. However, it was recently demonstrated that structures called quasicrystals may also exhibit nontrivial topological behavior attributed to dimensions higher than that of the quasicrystal. While quasiperiodicity has received a lot of attention in the fields of crystallography and photonics, research into quasiperiodic elastic structures has been scarce. In this paper, we show how the concepts of quasiperiodicity may be applied to the design of topological mechanical metamaterials. We start by investigating the boundary modes present in quasiperiodic 1D phononic lattices. These modes have the interesting property of being localized at either one of the two different boundaries depending on the value of an additional parameter, which is remnant of the higher dimension. A smooth variation of this parameter in either time or a spatial dimension can lead to a robust transfer of energy between two sites of the structure. We present an idealized mechanical system composed by an array of coupled rods that may be used as a platform for realizing this kind of robust transfer of energy. These are preliminary investigations into a entirely new class of structures which may lead to novel engineering applications.
Shape Memory Materials I
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Damage evolution during actuation fatigue in shape memory alloys (SPIE Best Student Paper Award)
Francis R. Phillips, Robert Wheeler, Dimitris C. Lagoudas
Shape Memory Alloys (SMAs) are unique materials able to undergo a thermomechanically induced, reversible phase transformation. Additionally, SMA are subject to two types of fatigue, that is structural fatigue due to cyclic loading as experienced by most materials, as well as actuation fatigue due to repeated thermally induced phase transformation. The evolution of multiple material characteristics is presented over the actuation fatigue lifetime of NiTiHf actuators, including the accumulation of irrecoverable strain, the evolution of internal voids, and the evolution of the effective modulus of the actuator. The results indicate that all three of these material characteristics are clearly interconnected and careful analysis of each of these characteristics can help to understand the evolution of the others, as well as help to understand how actuation fatigue leads to ultimate failure of the actuator.
Shape memory alloy-actuated bistable composites for morphing structures
Venkata Siva C. Chillara, Marcelo J. Dapino
Laminated composites with orthogonally-applied mechanical prestress have been shown to exhibit two stable shapes where each shape is influenced by only one prestrained lamina. The application of mechanical prestress is associated with an irreversible non-zero stress state; when combined with smart materials with controllable stress-states, this results in multifunctionality in morphing composites. This study presents an experimental characterization of the shape transition or snap-through in mechanically-prestressed bistable laminates. Measurements, conducted using tensile testing and 3D motion capture, show that snap-through in these laminates is a multi-stage phenomenon. An active bistable morphing composite is demonstrated using NiTi shape memory wire actuators in push-pull configuration; activation of one wire resets the second wire as the composite morphs. The set of shape memory actuators not only actuate the composite in both directions, but also act as dampers that enable vibration-free shape transition.
Analytical model for a laminated shape memory alloy beam with piezoelectric layers
N. V. Viet, W. Zaki, R. Umer
We propose an analytical model for a laminated beam consisting of a superelastic shape memory alloy (SMA) core layer bonded to two piezoelectric layers on its top and bottom surfaces. The model accounts for forward and reverse phase transformation between austenite and martensite during a full isothermal loading-unloading cycle starting a full austenite in the SMA layer. In particular, the laminated composite beam has a rectangular cross section and is fixed at one end while the other end is subjected to a concentrated transverse force acting at the tip. The moment-curvature relation is analytically derived. The generated electric displacement output from the piezoelectric layers is then determined using the linear piezoelectric theory. The results are compared to 3D simulations using finite element analysis (FEA). The comparison shows good agreement in terms of electric displacement, in general, throughout the loading cycle.
Additive Manufacturing I
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Influence of SLM on compressive response of NiTi scaffolds
Narges Shayesteh Moghaddam, Soheil Saedi, Amirhesam Amerinatanzi, et al.
Porous Nickel-Titanium shape memory alloys (NiTi-SMAs) have attracted much attention in biomedical applications due to their high range of pure elastic deformability (i.e., superelasticity) as well as their bone-level modulus of elasticity (E≈12-20 GPa). In recent years, Selective Laser Melting (SLM) has been used to produce complex NiTi components. The focus of this study is to investigate the superelasticity and compressive properties of SLM NiTi-SMAs. To this aim, several NiTi components with different level of porosities (32- 58%) were fabricated from Ni50.8Ti (at. %) powder via SLM PXM by Phenix/3D Systems, using optimum processing parameter (Laser power-P=250 W, scanning speed-v=1250mm/s, hatch spacing-h=120μm, layer thickness-t=30μm). To tailor the superelasticity behavior at body temperature, the samples were solution annealed and aged for 15 min at 350°C. Then, transformation temperatures (TTs), superelastic response, and cyclic behavior of NiTi samples were studied. As the porosity was increased, the irrecoverable strain was observed to be higher in the samples. At the first superelastic cycle, 3.5%, 3.5%, and 2.7% strain recovery were observed for the porosity levels of 32%, 45%, and 58%, respectively. However, after 10 cycles, the superelastic response of the samples was stabilized and full strain recovery was observed. Finally, the modulus of elasticity of dense SLM NiTi was decreased from 47 GPa to 9 GPa in the first cycle by adding 58% porosity.
Electrical conductivity and piezoresistive response of 3D printed thermoplastic polyurethane/multiwalled carbon nanotube composites
Cameron J. Hohimer, Gayaneh Petrossian, Amir Ameli, et al.
Additive manufacturing (AM) is an emerging field experiencing rapid growth. This paper presents a feasibility study of using fused-deposition modeling (FDM) techniques with smart materials to fabricate objects with sensing and actuating capabilities. The fabrication of objects with sensing typically requires the integration and assembly of multiple components. Incorporating sensing elements into a single FDM process has the potential to significantly simplify manufacturing. The integration of multiple materials, especially smart materials and those with multi-functional properties, into the FDM process is challenging and still requires further development.

Previous works by the authors have demonstrated a good printability of thermoplastic polyurethane/multiwall carbon nanotubes (TPU/MWCNT) while maintaining conductivity and piezoresistive response. This research explores the effects of layer height, nozzle temperature, and bed temperature on the electrical conductivity and piezoresistive response of printed TPU/MWCNT nanocomposites. An impedance analyzer was used to determine the conductivity of printed samples under different printing conditions from 5Hz-13MHz. The samples were then tested under compression loads to measure the piezoresistive response.

Results show the conductivity and piezoresistive response are only slightly affected by the print parameters and they can be largely considered independent of the print conditions within the examined ranges of print parameters. This behavior simplifies the printing process design for TPU/MWCNT complex structures. This work demonstrates the possibility of manufacturing embedded and multidirectional flexible strain sensors using an inexpensive and versatile method, with potential applications in soft robotics, flexible electronics, and health monitoring.
Origami Materials
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Modeling and optimization of self-folding origami structures undergoing large deformation (Conference Presentation)
Markus Geiss
Emerging manufacturing techniques provide unprecedented design freedom that traditional design methods do not entirely utilize. Therefore, sophisticated design tools are needed that take advantage of the increased flexibility of these manufacturing techniques to realize parts with complex geometry at acceptable cost. Topology optimization being one of these tools is used in this work to automate the design process of self-folding 3D origami structures undergoing large deformation. A gradient-based level-set topology optimization approach is adopted to describe the geometry evolving throughout the optimization process. The eXtended Finite Element Method (XFEM), an immersed boundary technique, is employed to predict the structural response using a well-resolved geometry representation and spatial discretization. A large-strain mechanical model together with higher-order finite elements is utilized to capture the physical behavior of self-folding structures where self-actuation is caused by internal swelling-strains. The complex geometries and non-intuitive material layouts resulting from the optimization process are then fabricated and tested via direct 4D printing. During this additive manufacturing approach, a pre-programmed swelling strain is directly printed into certain parts of the structure eliminating the need for mechanical or thermal training to generate self-folding. After an in-depth discussion of the modeling and optimization approach, examples of optimized origami structures are presented and comparisons against direct 3D printed samples are made.
Buckling behavior of origami unit cell facets under compressive loads
Mohamed Ali Emhmed Kshad, Hani E. Naguib
Origami structures as cores for sandwich structures are designed to withstand the compressive loads and to dissipate compressive energy. The deformation of the origami panels and the unit cell facets are the primary factors behind the compressive energy dissipation in origami structures. During the loading stage, the origami structures deform through the folding and unfolding process of the unit cell facets, and also through the plastic deformation of the facets. This work presents a numerical study of the buckling behavior of different origami unit cell elements under compressive loading. The studied origami configurations were Miura and Ron-Resch-like origami structures. Finite element package was used to model the origami structures. The study investigated the buckling behavior of the unit cell facets of two types of origami structures Miura origami and Ron-Resch-Like origami structures. The simulation was conducted using ANSYS finite element software, in which the model of the unit cell represented by shell elements, and the eigenvalues buckling solver was used to predict the theoretical buckling of the unit cell elements.
Optically and magnetically induced self-folding polymer composite prepared by electrospinning technique (Conference Presentation)
Kuei-Ren Chen, Wei-Hao Wang, Ta-I Yang
A simple method was developed to fabricate magnetically and optically responsive actuators utilizing composites of polycaprolactone (PCL) and polydimethylsiloxane (PDMS) loaded with iron oxide (Fe3O4) nanoparticles. An electrospinning technique enables to obtain Fe3O4 / PCL/PDMS composites with nanofiber structure. We demonstrate the self-folding ability of our developed composites upon exposing to external alternating magnetic field (AMF) or light. The self-folding behavior contributed to the structure change and stress relaxation of the composites, resulting from the temperature increase caused by the AMF and light absorption properties of Fe3O4 nanoparticles. The findings in this work could provide new ideas to design advanced complex self-folding materials.
Dielectrics and Piezolectrics
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Phenomenological model for coupled multi-axial piezoelectricity
Yuchen Wei, Sergio Pellegrino
A quantitative calibration of an existing phenomenological model for polycrystalline ferroelectric ceramics is presented. The model relies on remnant strain and polarization as independent variables. Innovative experimental and numerical model identification procedures are developed for the characterization of the coupled electro-mechanical, multi-axial nonlinear constitutive law. Experiments were conducted on thin PZT-5A4E plates subjected to cross-thickness electric field. Unimorph structures with different thickness ratios between PZT-5A4E plate and substrate were tested, to subject the piezo plates to coupled electro-mechanical fields. Material state histories in electric field-strain-polarization space and stress-strain-polarization space were recorded. An optimization procedure is employed for the determination of the model parameters, and the calibrated constitutive law predicts both the uncoupled and coupled experimental observations accurately.
Uncertainty quantification for PZT bimorph actuators
Nikolas Bravo, Ralph C. Smith, John Crews
In this paper, we discuss the development of a high fidelity model for a PZT bimorph actuator used for micro-air vehicles, which includes the Robobee. We developed a high-fidelity model for the actuator using the homogenized energy model (HEM) framework, which quantifies the nonlinear, hysteretic, and rate-dependent behavior inherent to PZT in dynamic operating regimes. We then discussed an inverse problem on the model. We included local and global sensitivity analysis of the parameters in the high-fidelity model. Finally, we will discuss the results of Bayesian inference and uncertainty quantification on the HEM.
Active subspace uncertainty quantification for a polydomain ferroelectric phase-field model
Lider S. Leon, Ralph C. Smith, Paul Miles, et al.
Quantum-informed ferroelectric phase field models capable of predicting material behavior, are necessary for facilitating the development and production of many adaptive structures and intelligent systems. Uncertainty is present in these models, given the quantum scale at which calculations take place. A necessary analysis is to determine how the uncertainty in the response can be attributed to the uncertainty in the model inputs or parameters. A second analysis is to identify active subspaces within the original parameter space, which quantify directions in which the model response varies most dominantly, thus reducing sampling effort and computational cost. In this investigation, we identify an active subspace for a poly-domain ferroelectric phase-field model. Using the active variables as our independent variables, we then construct a surrogate model and perform Bayesian inference. Once we quantify the uncertainties in the active variables, we obtain uncertainties for the original parameters via an inverse mapping. The analysis provides insight into how active subspace methodologies can be used to reduce computational power needed to perform Bayesian inference on model parameters informed by experimental or simulated data.
Additive Manufacturing II
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Solvent sensitivity of smart 3D-printed nanocomposite liquid sensor
Nahal Aliheidari, Amir Ameli, Petra Pötschke
Fused deposition modeling (FDM) is one of the 3D printing methods that has attracted significant attention. In this method, small and complex samples with nearly no limitation in geometry can be fabricated layer by layer to form end-use parts. This work investigates the liquid sensing behavior of FDM printed flexible thermoplastic polyurethane, TPU filled with multiwalled carbon nanotubes, MWCNTs. The sensing capability of printed TPU-MWCNT was studied as a function of MWCNT content and infill density in response to different solvents, i.e., ethanol, acetone and toluene. The solvents were selected based on their widespread use and importance in medical and industrial applications. U-shaped liquid sensors with 2, 3 and 4wt.% MWCNT content were printed at three different infill densities of 50, 75 and 100%. Solvent sensitivity was then characterized by immersing the sensors in the solvents and measuring the resistance evolution over 25s. The results indicated a sensitivity order of acetone > toluene > ethanol, which was in agreement with the predictions of FloryHiggins solubility equation. For all the solvents, the sensitivity was enhanced as the infill density of the printed samples was decreased. This was attributed to the increased surface area to volume ratio and shortened diffusion paths. The MWCNT content was also observed to have a profound effect on the sensitivity; in samples with partial infill, the sensitivity was found to be inversely proportional to the MWCNT content, such that the highest resistance change was obtained for nanocomposites with the lowest MWCNT content of 2wt.%. For instance, a resistance increase of more than 10 times was obtained in 25 s once TPU-2wt.%MWCNT with 50% infill was tested against acetone. The results of this work reveals that highly sensitive liquid sensors can be fabricated with the aid of 3D printing without the need for complex processing methods.
Selective laser melting of Ni-rich NiTi: selection of process parameters and the superelastic response
Narges Shayesteh Moghaddam, Soheil Saedi, Amirhesam Amerinatanzi, et al.
Material and mechanical properties of NiTi shape memory alloys strongly depend on the fabrication process parameters and the resulting microstructure. In selective laser melting, the combination of parameters such as laser power, scanning speed, and hatch spacing determine the microstructural defects, grain size and texture. Therefore, processing parameters can be adjusted to tailor the microstructure and mechanical response of the alloy. In this work, NiTi samples were fabricated using Ni50.8Ti (at.%) powder via SLM PXM by Phenix/3D Systems and the effects of processing parameters were systematically studied. The relationship between the processing parameters and superelastic properties were investigated thoroughly. It will be shown that energy density is not the only parameter that governs the material response. It will be shown that hatch spacing is the dominant factor to tailor the superelastic response. It will be revealed that with the selection of right process parameters, perfect superelasticity with recoverable strains of up to 5.6% can be observed in the as-fabricated condition.
Ultrasonic alignment of microparticles in nozzle-like geometries
Molly A. Whittaker, Erin R. Dauson, Jaime Parra-Raad, et al.
Additive manufacturing (3-D printing) is presently limited by the mechanical properties of the materials, such as polymer resins, that are otherwise efficient and economical for part-forming. Reinforcing the resin with microscale fibers and/or particles would be an effective mechanism to achieve desired mechanical properties such as strength and ductility. Our work combines standing wave ultrasonics and microfluidics to align microparticles in devices that can act as print nozzles, based in part on our prior work with cell sorting. In this paper three different approaches are presented illustrating different engineering tradeoffs, and demonstrating laboratory results of particle alignment. First acoustic resonators are discussed, in which the ultrasonic standing waves result mostly from the mechanical properties of the microfluidic structure, excited by a piezoceramic transducer. Next non-resonant microfluidic structures are discussed, in which ultrasonic standing waves are produced directly by symmetrical transducer deployment. Finally, devices that combine nozzle-like structures, which themselves are suitable acoustic resonators, subjected to symmetrical ultrasonic excitation are presented. We will show that all three configurations will align microparticles, and discuss the tradeoffs among them for subsequent configuration of a print nozzle.
Soft embedded micropillar arrays for actuation and sensing (Conference Presentation)
We propose a new strategy for dielectric elastomers based on three dimensional electrodes (in liquid, gel, and solid states) created by microstructured networks of pillar arrays. We demonstrate fabrication through the use of existing MEMS electroding technology and soft nanolithography techniques. The dielectric elastomer transducers can be configured for capacitive sensing or electrostatic actuation. In the proposed work, integrated microstructures form a network of soft microcapacitor arrays driven by rational combinations of liquid electronic conductors, ionic conducting gels, ionic conducting liquids, and stretchable metallic films. Fluid electrodes are a viable consideration for encapsulated material systems such as the one considered here. Micropillar arrays are fabricated using a soft nanolithography technique whereby the pillar structure is electroded with sputtered gold and eutectic Gallium–Indium (EGaIn) liquid metal. This creates a novel configuration whereby the working electrodes are integrated within the structure itself. We utilize an electrochemical technique to coat the cilia-like micropillar surface with EGaIn. The electroded micropillars enable large sensor stretches up to 60%. When configured for actuation, the array generates macroscopic deformations in response to lower voltages (< 1kV) than typically prescribed for dielectric elastomers (i.e. 2kV – 10 kV). When configured for sensing, our results show increased sensitivity in comparison to monolithic DE sensors. The micropillar sensor has high sensitivity (1.2 kPa-1) in the tactile sensing regime (<10kPa). We employ an experimental approach to investigate the influence of pillar size, shape, and aspect ratio on electromechanical performance. This paper presents characteristics of the sensing and actuation response.
Electromechanical modeling and experimental verification of a directly printed nanocomposite
Piezoelectric materials are currently among the most promising building blocks of sensing, actuating and energy harvesting systems. However, these materials are limited in applications due to difficulty in machining and casting it on to curve surfaces. To mitigate this issue, one method is through additive manufacturing (direct printing) of piezoelectric nanocomposite in which piezoelectric nanomaterials are embedded into a polymer matrix. Although significant progress has been recently made in this area, modeling the electromechanical response of a directly printed nanocomposite remains a challenge. Thus the objective of this study is to develop robust micromechanical and finite element models that allows the study of the electroelastic properties of a directly printed nanocomposite containing piezoelectric inclusions. Furthermore, the dependence of these properties on geometrical parameters such as aspect ratio and alignment of the active phase are investigated. The focus of this work is a demonstration of the effect gradual alignment of piezoelectric nanowires in a nanocomposite from randomly oriented to purely aligned improves the electroelastic properties of a directly printed nanocomposite. Finally, these models are verified through experimental measurement of electroelastic properties of the nanocomposites containing barium titanate nanowires in Polydimethylsiloxane (PDMS) polymer.
Mechanical evaluation of the SLM fabricated, stiffness-matched, mandibular bone fixation plates
Ahmadreza Jahadakbar, Narges Shayesteh Moghaddam, Amirhesam Amerinatanzi, et al.
The standard of the care for the treatment of mandibular segmental defects is the use of Ti-6Al-4V bone fixation plates and screws to immobilize the grafted bone and the host mandible. While Ti-6Al-4V bone fixation plates provide strong immobilization during the healing period, they may disturb the stress distribution in the repaired mandible. The highly stiff Ti-6Al-4V fixation carries a great portion of the load which was previously borne by the mandible, and stress shielding may occur on the surrounding cortical bone. Based on the bone remodeling theory, stress shielding causes bone resorption in the effected region and may eventually lead to the failure of the surgical reconstruction. To address this issue, we have developed a new generation of the patient-specific, porous NiTi bone fixation plates which benefit from stiffness-matching of the adjacent bone.

Using the CT scan data of the patient’s defective mandible, the geometry for the required bone fixation plates is designed and the stiffness of the surrounding regions is measured. By introducing specific level and type of porosity to the bone fixation plate, its stiffness can be tuned. Finite Element simulations has verified the reduced level of stress shielding on the reconstructed mandible, in case of using the proposed bone fixation plates.

Selective Lase Sintering has been used for fabrication of the porous NiTi bone fixation plates with six different levels of stiffness. Finite element simulations, and mechanical tests have been done to verify the performance of the fabricated parts resulting from our design and fabrication method.
Materials challenges for repeatable RF wireless device reconfiguration with microfluidic channels
Anthony S. Griffin, Nancy R. Sottos, Scott R. White
Recently, adaptive wireless devices have utilized displacement of EGaIn within microchannels as an electrical switching mechanism to enable reconfigurable electronics. Device reconfiguration using EGaIn in microchannels overcomes many challenges encountered by more traditional reconfiguration mechanisms such as diodes and microelectromechanical systems (MEMS). Reconfiguration using EGaIn is severely limited by undesired permanent shorting due to retention of the liquid in microchannels caused by wetting and rapid oxide skin formation. Here, we investigate the conditions which prevent repeatable electrical switching using EGaIn in microchannels. Initial contact angle tests of EGaIn on epoxy surfaces demonstrate the wettability of EGaIn on flat surfaces. SEM cross-sections of microchannels reveal adhesion of EGaIn residue to channel walls. Micro-computed tomography (microCT) scans of provide volumetric measurements of EGaIn remaining inside channels after flow cycling. Non-wetting coatings are proposed as materials based strategy to overcome these issues in future work.
Shape Memory Materials II
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Experimental and numerical investigation of the stable crack growth regime under pseudoelastic loading in shape memory alloys
Behrouz Haghgouyan, Sameer Jape, Ceylan Hayrettin, et al.
A combined experimental and numerical analysis of fracture and crack growth in SMAs is presented. Crack extension is investigated under mode-I, isothermal, monotonic, mechanical loading in near-equiatomic nickel- titanium (NiTi) SMA compact tension (CT) specimens. Stable crack growth is observed and the associated J-R curve is evaluated along with the crack initiation toughness. Finite element analysis (FEA) with an energetics based fracture toughness criterion is also carried out and crack is assumed to extend when crack-tip energy release rate reaches the material specific critical value. Fracture toughening behavior is observed during crack growth and is mainly associated with the energy dissipated by the progressively occurring phase transformation close to the moving crack tip. A comparison between the experimental and numerical results is presented.
Modeling of NiTiHf using finite difference method
Nazanin Farjam, Reza Mehrabi, Haluk Karaca, et al.
NiTiHf is a high temperature and high strength shape memory alloy with transformation temperatures above 100oC. A constitutive model based on Gibbs free energy is developed to predict the behavior of this material. Two different irrecoverable strains including transformation induced plastic strain (TRIP) and viscoplastic strain (VP) are considered when using high temperature shape memory alloys (HTSMAs). The first one happens during transformation at high levels of stress and the second one is related to the creep which is rate-dependent. The developed model is implemented for NiTiHf under uniaxial loading. Finite difference method is utilized to solve the proposed equations. The material parameters in the equations are calibrated from experimental data. Simulation results are captured to investigate the superelastic behavior of NiTiHf. The extracted results are compared with experimental tests of isobaric heating and cooling at different levels of stress and also superelastic tests at different levels of temperature. More results are generated to investigate the capability of the proposed model in the prediction of the irrecoverable strain after full transformation in HTSMAs.
Corrosion monitoring of NiTi alloy with small-amplitude potential intermodulation technique
M. Mohajeri, H. Castaneda, D. C. Lagoudas
The effects of thermal cycling on corrosion resistivity of Nickel-titanium shape memory alloy are studied. The corrosion properties of material has been studied with small-amplitude potential intermodulation technique at various temperatures from 0°C to 70°C. The corrosion properties has been determined from the system responses to a potential distortion to two sinusoidal waves. The Tafel slopes and corrosion rate at each temperature have been compared with the results of Linear Polarization Resistance (LPR), Electrochemical Impedance Spectroscopy (EIS) techniques. System response time for each technique and deviation from steady state conditions has been compared with obtained polarization resistance (Rp) values from EIS method. Differential Scanning Calorimetry (DSC) is used to determine the forward and reverse martensitic transformation temperatures. DSC graph shows martensitic phase at room temperature and temperature regime for experimental (from 0°C to 70°C).
Nanocomposites Applications
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Development and characterization of reduced graphene oxide films for transient electronics
Rasel Sheikh, Omkar Bhatkar, David Smith, et al.
Emerging interests in hardware security as well as environmental concerns have given rise to the field of transient or temporary electronics, which can be decommissioned by an external stimulus with minimal impact to the surrounding environment. In this study, an all graphene based film is produced by a one-step deposition process. The conversion of graphene oxide (GO) to reduced graphene oxide (rGO) depends on an interfacial reduction reaction. Control of processing conditions such as the underlying substrate, pH of GO and the film drying environment results in an ability to tailor the internal architecture of the films and their electronic properties. Furthermore, the ability to create masks for selective reduction of GO during deposition was also demonstrated, which was used to create intricate yet well-defined patterns and connections required in electronic circuits and devices. All graphene based freestanding films with selectively reduced GO were used in transient electronics application as circuitry and RFID tag patterns.
Anisotropic thermal conductivity of aligned GNPs/polymer composites: a finite element approach
Rui Li, Xingxing Xu, Bin Li, et al.
In this article, we propose a 3D FEM model to analyze the anisotropic thermal behavior of oriented GNPs/polymer composites. The model considers the effect of microstructural characteristics such as the shape and aspect ratio of filler, interfacial thermal resistance, volume fraction, dispersion state and orientation of GNPs dispersion to simulate a steady state heat flow in the composite. In the simulation model, the composite is treated as a cubic unit cell and GNPs are modeled as oblate spheroid with a long axis diameter of 1μm and the aspect ratio is in the range of 0.01 to 0.05. The oblate spheroids align in the cubic to represent the microstructure of the oriented GNPs/polymer composites. By varying the number of the GNPs in the representative unit cell, the volume fractions of fillers are determined. The simulation results show that the parallel thermal conductivity (//) increase in a nonlinear trend and the perpendicular thermal conductivity (⊥) is slightly linear increasing. Compared with experimental results, the trends predicted by the finite element models are consistent.
Magnetostrictive Materials
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Analysis of the mechanical behavior of single wall carbon nanotubes by a modified molecular structural mechanics model incorporating an advanced chemical force field
Oliver Eberhardt, Thomas Wallmersperger
The outstanding properties of carbon nanotubes (CNTs) keep attracting the attention of researchers from different fields. CNTs are promising candidates for applications e.g. in lightweight construction but also in electronics, medicine and many more. The basis for the realization of the manifold applications is a detailed knowledge of the material properties of the carbon nanotubes. In particular for applications in lightweight constructions or in composites, the knowledge of the mechanical behavior of the CNTs is of vital interest. Hence, a lot of effort is put into the experimental and theoretical determination of the mechanical material properties of CNTs. Due to their small size, special techniques have to be applied. In this research, a modified molecular structural mechanics model for the numerical determination of the mechanical behavior of carbon nanotubes is presented. It uses an advanced approach for the geometrical representation of the CNT structure while the covalent bonds in the CNTs are represented by beam elements. Furthermore, the model is specifically designed to overcome major drawbacks in existing molecular structural mechanics models. This includes energetic consistency with the underlying chemical force field. The model is developed further to enable the application of a more advanced chemical force field representation. The developed model is able to predict, inter alia, the lateral and radial stiffness properties of the CNTs. The results for the lateral stiffness are given and discussed in order to emphasize the progress made with the presented approach.
Uncertainty-enabled design of electromagnetic reflectors with integrated shape control
Samiul Haque, Laszlo P. Kindrat, Li Zhang, et al.
We implemented a computationally efficient model for a corner-supported, thin, rectangular, orthotropic polyvinylidene fluoride (PVDF) laminate membrane, actuated by a two-dimensional array of segmented electrodes. The laminate can be used as shape-controlled electromagnetic reflector and the model estimates the reflector’s shape given an array of control voltages. In this paper, we describe a model to determine the shape of the laminate for a given distribution of control voltages. Then, we investigate the surface shape error and its sensitivity to the model parameters. Subsequently, we analyze the simulated deflection of the actuated bimorph using a Zernike polynomial decomposition. Finally, we provide a probabilistic description of reflector performance using statistical methods to quantify uncertainty. We make design recommendations for nominal parameter values and their tolerances based on optimization under uncertainty using multiple methods.
Inverse magnetostrictive characteristics of Fe-Co composite materials using gas-nitriding process
Kenya Nakajima, Zhenjun Yang, Fumio Narita
The inverse magnetostrictive response, known as the Villari effect, of magnetostrictive materials is a change in magnetization due to an applied stress. It is commonly used for sensor applications. This work deals with the inverse magnetostrictive characteristics of Fe-Co bimetal plates that were subjected gas-nitriding process. Gas-nitriding was performed on bimetal plates for 30 min at 853 K as a surface heat treatment process. The specimens were cooled to room temperature after completing the nitriding treatment. Three-point bending tests were performed on the plates under a magnetic field. The changes on the magnetic induction of the plates due to the applied load are discussed. The effect of the nitriding treatment on the inverse magnetostrictive characteristics, magnetostrictive susceptibility, and magnetic hysteresis loop was examined. Our work represents an important step forward in the development of magnetostrictive sensor materials.
Performance prediction for a magnetostrictive actuator using a simplified model
Iron-Gallium alloys (Galfenol) are promising transducer materials that combine high magnetostriction, desirable mechanical properties, high permeability, and a wide operational temperature range. Most of all, the material is capable of operating under tensile stress, and is relatively resistant to shock. These materials are generally characterized using a solid, cylindrically-shaped specimen under controlled compressive stress and magnetization conditions. Because the magnetostriction strongly depends on both the applied stress and magnetization, the characterization of the material is usually conducted under controlled conditions so each parameter is varied independently of the other. However, in a real application the applied stress and magnetization will not be maintained constant during operation. Even though the controlled characterization measurement gives insight into standard material properties, usage of this data in an application, while possible, is not straight forward. This study presents an engineering modeling methodology for magnetostrictive materials based on a piezo-electric governing equation. This model suggests phenomenological, nonlinear, three-dimensional functions for strain and magnetic flux density responses as functions of applied stress and magnetic field. Load line performances as a function of maximum magnetic field input were simulated based on the model. To verify the modeling performance, a polycrystalline magnetostrictive rod (Fe-Ga alloy, Galfenol) was characterized under compressive loads using a dead-weight test setup, with strain gages on the rod and a magnetic field driving coil around the sample. The magnetic flux density through the Galfenol rod was measured with a sensing coil; the compressive loads were measured using a load cell on the bottom of the Galfenol rod. The experimental results are compared with the simulation results using the suggested model, showing good agreement.
“Shape function + memory mechanism”-based hysteresis modeling of magnetorheological fluid actuators
Li-Jun Qian, Peng Chen, Fei-Long Cai, et al.
A hysteresis model based on “shape function + memory mechanism” is presented and its feasibility is verified through modeling the hysteresis behavior of a magnetorheological (MR) damper. A hysteresis phenomenon in resistor-capacitor (RC) circuit is first presented and analyzed. In the hysteresis model, the “memory mechanism” originating from the charging and discharging processes of the RC circuit is constructed by adopting a virtual displacement variable and updating laws for the reference points. The “shape function” is achieved and generalized from analytical solutions of the simple semi-linear Duhem model. Using the approach, the memory mechanism reveals the essence of specific Duhem model and the general shape function provides a direct and clear means to fit the hysteresis loop. In the frame of the structure of a “Restructured phenomenological model”, the original hysteresis operator, i.e., the Bouc-Wen operator, is replaced with the new hysteresis operator. The comparative work with the Bouc-Wen operator based model demonstrates superior performances of high computational efficiency and comparable accuracy of the new hysteresis operator-based model.
Mechanics of Multifunctional Materials
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Synchronous separation, seaming, sealing and sterilization (S4) using brazing for sample containerization and planetary protection
The return of samples back to Earth in future missions would require protection of our planet from the risk of bringing uncontrolled biological materials back with the samples. This protection would require “breaking the chain of contact (BTC)”, where any returned material reaching Earth for further analysis would have to be sealed inside a container with extremely high confidence. Therefore, the acquired samples would need to be contained while destroying any potential biological materials that may contaminate the external surface of the container. A novel process that could be used to contain returning samples has been developed and demonstrated in a quarter scale size. The process consists of brazing using non-contact induction heating that synchronously separates, seams, seals and sterilizes (S4) the container. The use of brazing involves melting at temperatures higher than 500°C and this level of heating assures sterilization of the exposed areas since all carbon bonds (namely, organic materials) are broken at this temperature. The mechanism consists of a double wall container with inner and outer shells having Earth-clean interior surfaces. The process consists of two-steps, Step-1: the double wall container halves are fabricated and brazed (equivalent to production on Earth); and Step-2 is the S4 process and it is the equivalent to the execution on-orbit around Mars. In a potential future mission, the double wall container would be split into two halves and prepared on Earth. The potential on-orbit execution would consist of inserting the orbiting sample (OS) container into one of the halves and then mated to the other half and brazed. The latest results of this effort will be described and discussed in this manuscript.
The effects of surface topography control using liquid crystal elastomers on bodies in flow
Michael Settle, Tyler Guin, Richard Beblo, et al.
Surface topography control has use across many applications including delayed separation of flow via selective boundary-layer tripping. Recently, advances with liquid crystal elastomers (LCE) have been leveraged for controlled, repeatable, out-of-plane deformations that could enable these topographical changes. An aligned LCE deforms when heated, associated with a loss in order. Circumferential patterns fabricated through the thickness of the LCE film yield a predictable conical out-of-plane deformation that can control surface topography. This study focuses on the experimental investigation of LCE behavior for flow control. Initially, the deformations of LCE samples 1/2” in diameter and 50 µm thick were characterized using Digital Image Correlation under uniform positive and negative gauge pressures at various temperatures. Surface topography showed strong dependence on boundary conditions, sample dimensions, and pattern location relative to the applied boundary conditions, informing adjustment of the LCE of the chemistry to produce higher modulus and glassy materials. As an initial demonstration of the ability to control flow, Then, to demonstrate the potential for flow control, 3D printed cylinders with varying arrangements of representative topographical features were characterized in a wind tunnel with Particle Image Velocimetry. Results showed that features with a maximum deflection height of 1.5 mm in a two-row arrangement can form an asymmetric wake about a 73 mm diameter cylinder that reduces drag while generating lift. These results inform subsequent investigation of active LCE elements on a cylinder that are currently under examination.
Strength and failure analysis of composite-to-composite adhesive bonds with different surface treatments
Nikhil Paranjpe, Mohammed Alamir, Abdullah Alonayni, et al.
Adhesives are widely utilized materials in aviation, automotive, energy, defense, and marine industries. Adhesive joints are gradually supplanting mechanical fasteners because they are lightweight structures, thus making the assembly lighter and easier. They also act as a sealant to prevent a structural joint from galvanic corrosion and leakages. Adhesive bonds provide high joint strength because of the fact that the load is distributed uniformly on the joint surface, while in mechanical joints, the load is concentrated at one point, thus leading to stress at that point and in turn causing joint failures. This research concentrated on the analysis of bond strength and failure loads in adhesive joint of composite-to-composite surfaces. Different durations of plasma along with the detergent cleaning were conducted on the composite surfaces prior to the adhesive applications and curing processes. The joint strength of the composites increased about 34% when the surface was plasma treated for 12 minutes. It is concluded that the combination of different surface preparations, rather than only one type of surface treatment, provides an ideal joint quality for the composites.
Isolation of aramid nanofibers for high strength multiscale fiber reinforced composites
Jiajun Lin, Brendan A. Patterson, Mohammad H. Malakooti, et al.
Aramid fibers are famous for their high specific strength and energy absorption properties and have been intensively used for soft body armor and ballistic protection. However, the use of aramid fiber reinforced composites is barely observed in structural applications. Aramid fibers have smooth and inert surfaces that are unable to form robust adhesion to polymeric matrices due to their high crystallinity. Here, a novel method to effectively integrate aramid fibers into composites is developed through utilization of aramid nanofibers. Aramid nanofibers are prepared from macroscale aramid fibers (such as Kevlar®) and isolated through a simple and scalable dissolution method. Prepared aramid nanofibers are dispersible in many polymers due to their improved surface reactivity, meanwhile preserve the conjugated structure and likely the strength of their macroscale counterparts. Simultaneously improved elastic modulus, strength and fracture toughness are observed in aramid nanofiber reinforced epoxy nanocomposites. When integrated in continuous fiber reinforced composites, aramid nanofibers can also enhance interfacial properties by forming hydrogen bonds and π-π coordination to bridge matrix and macroscale fibers. Such multiscale reinforcement by aramid nanofibers and continuous fibers results in strong polymeric composites with robust mechanical properties that are necessary and long desired for structural applications.
Influence of material anisotropy on the hydroelastic response of composite plates in water
Deniz Tolga Akcabay, Yin Lu Young
Flexible lightweight plate-like lifting surfaces in external flows have a diverse range of use from propelling and controlling marine and aerospace vehicles to converting wind and ocean energy to electrical energy. Design and analysis of such structures are complex for underwater applications where the water density is much higher than air. The hydrodynamic loads, which vary with the inflow speed, can significantly alter the dynamic response and stability. This paper focuses on the hydroelastic response of composite plates in water. The results show that the dynamics and stability of the structure can be significantly modified by taking advantage of the material anisotropic; on the contrary, careless composite material designs may lead to unwanted dynamic instability failures. The resonance frequencies, divergence speeds, and fluid loss coefficients change with material anisotropy and hydrodynamic loads. The resonance frequencies are much lower in water than in air. The critical divergence speed increases, if the principal fiber direction is oriented towards the inflow. Hydrodynamic damping is shown to be much higher than the material damping, and tend to increase with flow speed and to decrease with increasing modal frequency. The paper derives Response Amplitude Operators (RAOs) for sample composite plates in water and use them to predict the motion response when subject to stochastic flow excitations. We show how material anisotropy can be used to passively tailor the plate vibration response spectrum to limit or enhance flow-induced vibrations of the plate depending on the desired applications.
Evaluation of thermally-aged carbon fiber/epoxy composites using acoustic emission, electrical resistance, contact angle and thermogram
J. M. Park, P. S. Shin, J. H. Kim, et al.
Interfacial and mechanical properties of thermal aged carbon fiber reinforced epoxy composites (CFRP) were evaluated using acoustic emission (AE), electrical resistance (ER), contact angle (CA) and thermogram measurements. Unidirectional (UD)-composites were aged at 200, 300, and 400 °C to produce different interfacial conditions. The interfacial degradation was identified by Fourier transform infrared (FT-IR) spectroscopy after different thermal aging. AE and ER of UD composites were measured along 0, 30, 60 and 90 °. Changes in wavespeed, with thermal aging, were calculated using wave travel time from AE source to AE sensor and the changes in ER were measured. For a thermogram evaluation, the composites were laid upon on a hotplate and the increase in the surface temperature was measured. Static contact angle were measured after different thermal aging and elapsed times to evaluate wettability. Interlaminar shear Strength (ILSS) and tensile strength at transverse direction tests were also performed to explore the effects of thermal aging on mechanical and interfacial properties. While thermal aging of CFRPs was found to affect all these properties, the changes were particularly evident at 400 °C.
Physically Responsive Materials
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Various design approaches to achieve electric field-driven segmented folding actuation of electroactive polymer (EAP) sheets
Electroactive polymer (EAPs) based technologies have shown promise in areas such as artificial muscles, aerospace, medical and soft robotics. In this work, we demonstrate ways to harness on-demand segmented folding actuation from pure bending of relaxor-ferroelectric P(VDF-TrFE-CTFE) based films, using various design approaches, such as ‘stiffener’ and ‘notch’ based approaches. The in-plane actuation of the P(VDF-TrFE-CTFE) is converted into bending actuation using unimorph configurations, where one passive substrate layer is attached to the active polymer. First, we experimentally show that placement of thin metal strips as stiffener in between active EAPs and passive substrates leads to segmented actuation as opposed to pure bending actuation; stiffeners made of different materials, such as nickel, copper and aluminum, are studied which reveals that a higher Young’s modulus favors more pronounced segmented actuation. Second, notched samples are prepared by mounting passive substrate patches of various materials on top of the passive layers of the unimorph EAP actuators. Effect of notch materials, size of the notches and position of the notches on the folding actuation are studied. The motion of the human finger inspires a finger-like biomimetic actuator, which is realized by assigning multiple notches on the structure; finite element analysis (FEA) is also performed using COMSOL Multiphysics software for the notched finger actuator. Finally, a versatile soft-gripper is developed using the notched approach to demonstrate the capability of a properly designed EAP actuator to hold objects of various sizes and shapes.
Time-dependent chemo-electro-mechanical behavior of hydrogel-based structures
Peter Leichsenring, Thomas Wallmersperger
Charged hydrogels are ionic polymer gels and belong to the class of smart materials. These gels are multiphasic materials which consist of a solid phase, a fluid phase and an ionic phase. Due to the presence of bound charges these materials are stimuli-responsive to electrical or chemical loads. The application of electrical or chemical stimuli as well as mechanical loads lead to a viscoelastic response. On the macroscopic scale, the response is governed by a local reversible release or absorption of water which, in turn, leads to a local decrease or increase of mass and a respective volume change.

Furthermore, the chemo-electro-mechanical equilibrium of a hydrogel depends on the chemical composition of the gel and the surrounding solution bath. Due to the presence of bound charges in the hydrogel, this system can be understood as an osmotic cell where differences in the concentration of mobile ions in the gel and solution domain lead to an osmotic pressure difference.

In the present work, a continuum-based numerical model is presented in order to describe the time-dependent swelling behavior of hydrogels. The numerical model is based on the Theory of Porous Media and captures the fluid-solid, fluid-ion and ion-ion interactions. As a direct consequence of the chemo-electro-mechanical equilibrium, the corresponding boundary conditions are defined following the equilibrium conditions. For the interaction of the hydrogel with surrounding mechanical structures, also respective jump condtions are formulated. Finaly, numerical results of the time-dependent behavior of a hydrogel-based chemo-sensor will be presented.
Multifunctional Materials Applications
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Optimal power, power limit, and damping of vibration piezoelectric power harvesters
Power harvesting describes the process of acquiring the ambient energy surrounding a system and converting it into usable electrical energy. Much of the work over the past two decades has focused on the conversion of ambient vibration energy sources using piezoelectric, electromagnetic and electrostatic transduction. Attempts were made to obtain a general model that could be applied to any transduction mechanism. Of the most interest is an electromagnetic generator model that was used by many researchers to model piezoelectric power harvesters. Two major results from the model are the power limit expression and the equal relationship between the electrically induced damping and the mechanical damping to reach the power limit. However, piezoelectric power harvesters cannot be accurately modeled by this electromagnetic model due to the essential difference in physics. There have also been attempts to obtain the power limit expression based on piezoelectric relationships, but they either neglect the piezoelectric backward coupling to the structure, or assume the power limit occurs at the resonance of the system. This paper obtains the power limit expression based on the piezoelectric coupled equations without those assumptions. In addition, the relationship between the electrically induced damping and mechanical damping at the power limit is studied. Furthermore, a closed-form criterion is derived and proposed to define strongly and weakly coupling power harvesters, whose differences in power characteristics are explained through analytical and numerical analysis. While most of the discussion is focused on linear power harvesters connected to a resistive circuit, the aim of this paper is to provide a comprehensive and deep understanding of this simple configuration, answers to important questions, and a starting point to develop a more general theory on power harvesters because similar system characteristics are observed in power harvesters with more complexities.
Interfacial characterization of flexible hybrid electronics
Flexible Hybrid Electronics (FHEs) are the new generation of electronics combining flexible plastic film substrates with electronic devices. Besides the electrical features, design improvements of FHEs depend on the prediction of their mechanical and failure behavior. Debonding of electronic components from the flexible substrate is one of the most common and critical failures of these devices, therefore, the experimental determination of material and interface properties is of great importance in the prediction of failure mechanisms. Traditional interface characterization involves isolated shear and normal mode tests such as the double cantilever beam (DCB) and end notch flexure (ENF) tests. However, due to the thin, flexible nature of the materials and manufacturing restrictions, tests mirroring traditional interface characterization experiments may not always be possible. The ideal goal of this research is to design experiments such that each mode of fracture is isolated. However, due to the complex nonlinear nature of the response and small geometries of FHEs, design of the proper tests to characterize the interface properties can be significantly time and cost consuming. Hence numerical modeling has been implemented to design these novel characterization experiments. This research involves loading case and specimen geometry parametric studies using numerical modeling to design future experiments where either shear or normal fracture modes are dominant. These virtual experiments will provide a foundation for designing similar tests for many different types of flexible electronics and predicting the failure mechanism independent of the specific FHE materials.
Poster Session
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Evaluation of oil-leakage of multi-layered resin-hose clamped with metal nipple and sleeve
Kenta Matsuoka, Kazuya Okubo, Toru Fujii, et al.
The purpose of this study is to investigate the path of occurred oil-leakage of multi-layered resin-hose as one of multifunctional materials around the caulked joint with a metal nipple and sleeve when excessive cyclic internal pressure was applied onto the hose. Equivalent cyclic axial tensile force was substitutively applied to the hose, where same degree of normal stress was produced in longitudinal direction. Excessive 3 and 5 times of the standard load was applied to the hose. Cyclic loading was paused at every 1000 and 10000 cycles and then designed internal pressure was applied to the hose by a hand-operated pump with water in order to check whether the leakage was occurred around the joint and surface of the hose for safety evaluation. Cyclic fatigue life was defined as the number of loading cycles in which the leakage and the initial damage which was the passage of the ultrasonic wave was observed on the cyclic test. Test results showed the fatigue life at which leakage of water was observed was increased 20 times in case of K=3 compared to that in case of K=5. The cycles of initial damage detected by the ultrasonic wave were passed was increased 3.3 times in case of K=3 compared to that in case of K=5. The fluorescent agent penetrated from the core layer of resin hose to the reinforcement layer in which a half cross section along longitudinal direction in failed specimens was observed after the leak test. The original specimens had the gap between the resin-hose and the nipple and then the gap extended and connected during fatigue cyclic. In this study, it was observed that oil was leaked through narrow gap between the nipple and core layer of resin hose.
Effect of the carbonyl iron particles on acoustic absorption properties of magnetic polyurethane foam
Jialu Geng, Caiping Wang, Honglang Zhu, et al.
Elastomeric matrix embedded with magnetic micro-sized particles has magnetically controllable properties, which has been investigated extensively in the last decades. In this study we develop a new magnetically controllable elastomeric material for acoustic applications at lower frequencies. The soft polyurethane foam is used as matrix material due to its extraordinary elastic and acoustic absorption properties. One-step method is used to synthesize polyurethane foam, in which all components including polyether polyols 330N, MDI, deionized water, silicone oil, carbonyl iron particle (CIP) and catalyst are put into one container for curing. Changing any component can induce the change of polyurethane foam’s properties, such as physical and acoustic properties. The effect of the content of MDI on acoustic absorption is studied. The CIPs are aligned under extra magnetic field during the foaming process. And the property of polyurethane foam with aligned CIPs is also investigated. Scanning electron microscope (SEM) is used to observe the structure of pore and particle-chain. The two-microphone impedance tube and the transfer function method are used to test acoustic absorption property of the magnetic foams.
The electrical resistivity and percolation threshold of MWCNTs/polymer composites filled with a few aligned carbonyl iron particles
Shuai Dong, Xiaojie Wang
Conductive polymer composites (CPCs) consist of multi-walled carbon nanotubes (MWCNTs), a few carbonyl iron particles (CIPs) and polydimethylsiloxane (PDMS) are fabricated under a moderate magnetic field. The alignment of CIPs will change the structure of MWCNT network, and consequently the electrical properties of CPCs. The volume fraction of CIPs is fixed at 0.08 vol% at which CIPs will not directly participate in electric conduction. The electrical resistivity of CPCs and the changes of resistance versus strain are evaluated at various MWCNT volume fractions. The testing results show that a percolation threshold as low as 0.19 vol% is obtained due to the effect of aligned CIPs, comparing with 0.39 vol% of isotropic MWCNT/CIP/PDMS (prepared without magnetic field). Meanwhile, the anisotropic structure reduces the electrical resistivity by more than 80% when the MWCNT volume fractions is over the percolation threshold.
Numerical model for an epoxy beam reinforced with superelastic shape memory alloy wires
N. V. Viet, W. Zaki, R. Umer
We present a numerical solution for a smart composite beam consisting of an epoxy matrix reinforced with unidirectional superelastic shape memory alloy (SMA) fibers with uniform circular cross section. The beam is loaded by a tip load, which is then removed resulting in shape recovery due to superelasticity of the SMA wires. The analysis is carried out considering a representative volume element (RVE) of the beam consisting of one SMA wire embedded in epoxy. The analytical model is developed for a superelastic SMA/epoxy composite beam subjected to a complete loading cycle in bending. Using the proposed model, the moment-curvature profile, martensite volume fraction variation, and axial stress are determined. The results are validated against three-dimensional finite element analysis (3D FEA) for the same conditions. The proposed work is a contribution toward better understanding of the bending behavior of superelastic SMA-reinforced composites.
Characteristics of energy harvesting using BaTiO3/Cu laminates with changes in temperature
K. Mori, H. Takeuchi, F. Narita
The energy harvesting characteristics of piezoelectric/copper (BaTiO3/Cu) laminates rising from sharp temperature changes were investigated both numerically and experimentally. First, a phase field simulation was performed to determine the temperature-dependent piezoelectric coefficient and permittivity values. Then, the output voltages of the BaTiO3/Cu laminates were calculated for variations from room temperature to either a cryogenic temperature (77 K) or a higher temperature (333 K) using a 3D finite element simulation with the properties calculated from the phase field simulation. Finally, the output voltages of the piezoelectric BaTiO3/Cu laminates were measured for the same temperature changes and were compared to the simulation results.
Modeling the effects of strain profiles and defects on precessional magnetic switching in multiferroic heterostructures
Andres C. Chavez, Auni A. Kundu, Christopher S. Lynch, et al.
Strain-mediated multiferroic heterostructures relying on fast 180° precessional magnetic switching have been proposed as a pathway for energy efficient and high density memory/logic devices. However, proper device performance requires precisely timed high frequency (~GHz) voltage pulses dependent on the magnetization dynamics of the structure. In turn, the dynamic response of the device is greatly influenced by the device geometry, strain amplitude, and strain rate. Hence, we study the effects of increasing the voltage amplitude and application rate on the in-plane magnetization dynamics of a single-domain CoFeB ellipse (100 nm x 80 nm x 6 nm) on a 500 nm thick PZT substrate in addition to studying defects in the geometry. Both a coupled micromagnetics, electrostatics and elastodynamics finite element model and a conventional micromagnetics software was used to study the strain-induced magnetic response of the CoFeB ellipse. Both models predict increased 90° magnetic reorientation speed with increased strain amplitude and rate. However, the fully-coupled model predicts slower reorientation and incoherency in comparison to the uncoupled model. This occurs because the fully-coupled model can capture the expected strain gradients of a fabricated device while the micromagnetics model can only represent uniform strain states. Additional studies which introduce geometric defects result in faster precessional motion under the same strain amplitude and rate. This is attributed to localized changes in the magnetization that influence neighboring regions via exchange and demagnetization effects. The results of these studies can help design better devices that will be less sensitive to defects and voltage applications for future strain-mediated multiferroic devices.
Safety concerns in composite manufacturing and machining
Because of the superior properties, composites have been used in many industrial applications, including aerospace, wind turbines, ships, cars, fishing rods, storage tanks, swimming pool panels, and baseball bats. Each application may require different combinations of reinforcements and matrices, which make the manufacturing safety even more challenging while working on these substances. In this study, safety issues in composite manufacturing and machining were investigated in detail, and latest developments were provided for workers. The materials most frequently used in composite manufacturing, such as matrix (polyester, vinylester, phenolic, epoxies, methyl ethyl ketone peroxide, benzoil peroxide, hardeners, and solvents), and reinforcement materials (carbon, glass and Kevlar fibers, honeycomb and foams) can be highly toxic to human body. These materials can also be very toxic to the environment when dumped out uncontrollably, creating major future health and environmental concerns. Throughout the manufacturing process, workers inhale vapors of the liquid matrix, hardeners and solvents / thinners, as well as reinforcement materials (chopped fibers and particles) in airborne. Milling, cutting and machining of the composites can further increase the toxic inhalations of airborne composite particles, resulting in major rashes, irritation, skin disorders, coughing, severe eye and lung injury and other serious illnesses. The major portions of these hazardous materials can be controlled using appropriate personal protective equipment for the chemicals and materials used in composite manufacturing and machining. This study provides best possible safety practices utilized in composite manufacturing facilities for workers, engineers and other participants.
Sustainability of fiber reinforced laminate and honeycomb composites in manufacturing industries
Fiber reinforced polymer (FRP) composites provide a lot of benefits, including strength-to-weight ratio / light weight, superior mechanical properties, low maintenance, prolonged service life, as well as corrosion, fatigue and creep resistance. However, sustainability of the FRP composites have not been studied in detail in terms of long term productions in various industries, such as aerospace, wind energy, automotive and defense. Carbon fibers are relatively expensive because of the energy intensive production systems, and lack of easy production options, which forces many companies to recycle and reuse the FRP composites in the same or different manufacturing industries. This study mainly deals with two important issues, including the disposal of composite wastes generated during the manufacturing of composite parts, and the disposal of the products at the end of their useful life. It is believed that the carbon fibers in the used composites will have still high mechanical strengths to use in different composite manufacturing after its end of life. The major manufacturing costs come from the labor and raw materials, so using the recycled carbon fibers will make sustainable composite productions in other industries. This paper presents the current status and outlook of the FRP composite recycling and re-manufacturing techniques in the same or different industries. A future vision of the FRP composites will be investigated with sustainability point of views. This study will also mention about the sustainability issues in laminate and honeycomb composites, new product design and developments and potential applications in different manufacturing industries.